| 角色 | 饰演者 | 角色介绍 |
| Ash/May (voice: English version) | Veronica Taylor | |
| Max (voice: English version) | Amy Birnbaum | |
| Brock/James (voice: English version) | Eric Stuart | |
| Pikachu (voice) | 大谷育江 | |
| Jessie (voice: English version) | Rachael Lillis | |
| Meowth (voice: English version) | Madeleine Blaustein | |
| Narrator (voice: English version) | Mike Pollock | |
| Lucario (voice: English version) | Sean Schemmel | |
| Sir Aaron (voice: English version) | Jason Griffith | |
| Lt. Banks (voice: English version) | Oliver Wyman | |
| Freddy (voice: English version) | Darren Dunstan | |
| Mew (voice: English version) | 山寺宏一 | |
| Additional voices (voice) | Suzanne Goldfish | |
| Additional voices (voice) | Dan Green | |
| Additional voices (voice) | Rebecca Honig | |
| Additional voices (voice) | Bella Hudson | |
| Additional voices (voice) | Andrew Paull | |
| Wobbuffet/Taillow/Additional voices | Kayzie Rogers | |
| Additional voices (voice) | Lindsey Warner | |
| Mew (voice) | 兴梠里美 | |
| Registeel (voice) | Atsushi Kakehashi | |
| Regice (voice) | Kunihiro Kawamoto | |
| Regirock (voice) | Eiji Miyashita | |
| Lucario (voice: Japanese version) | 浪川大辅 |
