| 角色 | 饰演者 | 角色介绍 |
| Barbie (singing voice) | Skye Sweetnam | |
| Tia | Crystal Anderson | |
| Dawn (voice) | Anna Cummer | |
| Chem Teacher (voice) | Michael Daingerfield | |
| Stephanie (voice) | 海瑟·多克森 | |
| Courtney (voice) | Sarah Edmondson | |
| Todd (voice) | Andrew Francis | |
| Reagen (voice) | Maryke Hendrikse | |
| Kevin (voice) | Matt Hill | |
| Mr. Wexler/Popular boy #2 (voice) | Joe May | |
| Mr. Wexler/popular boy #2 (voice) | 约瑟夫·梅 | |
| Courtney | Sierra Richter | |
| Barbie (voice) | Kelly Sheridan | |
| Barbie | Katelyn Tarver | |
| Tia (voice) | Venus Terzo |
